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萘啶酮酸体系荧光法测定铕、铽、镝
Fluorimetric Determination of Europium, Terbium and Dysprosium With Nalidixic Acid System
【摘要】 本文研究了萘啶酮酸(NA)体系荧光法同时测定铕、铽、镝的最佳条件。在pH值75、3.0×10-4mol/LNA、激发波长342nm的条件下,可分别在612、546、576nm处测定铕、铽、镝,检测限可分别达到1.3、1.0、4.4μg/L。应用本法同时测定了混合稀土试样中铕、铽、镝,取得较满意的结果。
【Abstract】 This paper reports the optimum conditions for fluorometric determination of Eu3+, Tb3+, Dy3+ complexes with nalidixic acid and the effect of coexisting ions. The detection limit of Eu, Tb and Dy is 1. 3, 1.0, 4. 4μg/L, respectively. These three ions in mixed rare earth oxides were determined with this method. The results analysed agree well with those obtained by other methods.
【基金】 河北省自然科学基金
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1996年10期
- 【分类号】O657.3
- 【被引频次】11
- 【下载频次】72