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切花泥主成分的色谱-质谱联用分析
Analysis of Main Components of Flower Mud by Gas Chromatography-Mass Spectrometry
【摘要】 本文通过切花泥的高温裂解,利用色谱-质谱联用方法对其主成分进行了结构分析。实验比较了OV-101和SE-31二种石英毛细管柱对其分离效果的影响,质谱鉴定出的30种小分子,表明它主要是由酚醛树脂和少量聚乙二醇、异氰酸苯酯和胺类等有机物为基本原料组成的高分子聚合物,并简要讨论了主成分的质谱碎裂特征。结果进一步被红外光谱和元素分析所证实。
【Abstract】 In this paper, we have analyzed and identified the structure of main components of the flower mud by high-temperature pyrolysis and GC-MS. The effects on separation of the pyrolytic products were compared using quartz capilIary columns OV-1ol and SE-31. The experimental results via GC-MS, IR, and elemental analysis have shown that major materials of flower mud are composea of phenol-formaldehyde resin, polyethylene glycol, isocyanato benzenes, amines, etc.
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1996年10期
- 【分类号】O657.6
- 【被引频次】1
- 【下载频次】64