节点文献
以二乙氨基乙基交联葡聚糖凝胶为基质的铝荧光传感层
An Aluminum Fluorescence Sensing Layer Based on 2-(Diethylamino)Ethyl Sephadex as a Substrate
【摘要】 本文基于A13-离子对电价键固定在二乙氨基乙基交联葡聚糖凝胶(DEAESephadex)上的水杨基荧光酮的可逆荧光淬灭作用,研制了测定Al3-离子浓度的荧光传感层。其线性范围为20~150μg/L,重视性良好,响应速度快。该传感层已成功应用于水样和葡萄糖注射液中A13-离子的测定,并初步研究了荧光淬灭机理。
【Abstract】 A new fluorescence sensing layer for the determination of Al3- based on reversible fluorescence quenching of salicylfluorone immobilized electrostatically on 2-(diethylamino )-ethyl sephadex has been developed. Al3+ in solution from 20μg/L to 150μg/L can be determined. Besides a high reproducibility of optical signals, a short rcsponse time is realized.This sensing layer has been applied to the determination of Al3- in water samples and glucose injection. The mechanism of fluorescence quenching has been studied.
【基金】 国家自然科学基金
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1996年10期
- 【分类号】TP212
- 【被引频次】1
- 【下载频次】76