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亚硝酸根在钴(Ⅱ)-邻菲口罗啉络合物存在下的电催化还原

Electrocatalytic Reduction of Nitrite in The Presence of Complex of Cobalt(Ⅱ) and 1,10 Phenanthroline

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【作者】 同健党晓军力虎林

【Author】 Tong Jian Dang Xiaojun Li Hulin (Department of chemistry, Lanzhou University, Lanzhou 730000)

【机构】 兰州大学化学系

【摘要】 研究钴(Ⅱ)-邻菲口罗啉络合物Co(Phen)2+2在玻碳电极上的伏安行为和对亚硝酸根电化学还原的催化作用以及影响催化作用的因素

【Abstract】 The electrochemistry of cobalt(Ⅱ) 1,10 phenanthroline Co(Phen) 2+ 2 complex and its ability to electrocatalyze the reduction of nitrite were studied , we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.

【关键词】 亚硝酸根邻菲口罗啉电化学催化
【Key words】 NitritePhenanthrolineElectrocatalytic
【基金】 国家自然科学基金
  • 【分类号】O641.4
  • 【被引频次】4
  • 【下载频次】121
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