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化学键性质对机械合金化过程中非晶形成能力的影响

EFFECT OF CHEMICAL BONDING CHARACTER OF INTERMETALLIC COMPOUNDS ON THEIR GLASS FORMATION TENDENCY IN THE PROCESS OF MECHANICAL ALLOYING

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【作者】 郑明新张翔郑仲瑜

【Author】 ZHENG Mingxin;ZHANG Xiang;ZHENG Zhongyu(Tsinghua University)

【机构】 清华大学

【摘要】 研究了B2型金属间化合物FeAl和FeTi的机械合金化过程发现在相同的试验条件下,FeAl形成化学无序的固溶体,FeTi形成结构无序的非晶态。此现象可用FeAl的化学键为金属—离子混合键,而FeTi的化学键为金属—共价—离子混合键来解释。

【Abstract】 In this paper, the mechanical alloying process of two intermetallic compounds of the type B2 FeAl and FeTi has been investigated.It is found that FeAl forms a chemical-disordered solution, but FeTi exists in a structural-disordered noncrystalline state under the same experimental conditions. Such results can be explained by that FeAl is of the metallic-ionic mixed bonding and FeTi the metallic-covalent-ionic mixed one.

  • 【文献出处】 材料研究学报 ,CHINESE JOURNAL OF MATERIAL RESEARCH , 编辑部邮箱 ,1996年05期
  • 【分类号】TG139.8
  • 【下载频次】37
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