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赤霉素环氧衍生物的合成研究
THE APPROACH TO THE SYNTHESIS OF THE EPOXIDES OF GIBBERELLINS
【摘要】 以赤霉素GA_3为起始物,经十步,合成了赤霉素的环氧衍生物ent-13-乙酰氧基-1α,10α-环氧基-3β-羟基-1-甲基-20-去甲赤霉素-16-烯-7,19-二酸-7,19-二甲酯,这是一个新化合物.与此同时,还合成了其他三个新化合物,并通过1H-NMR、13C-NMR、MS等分析方法证实了它们的结构.
【Abstract】 The epoxides of gibberellin (ent-13-acetoxy-1α, 10α-epoxy-3β-hydroxy-1-methyl-20-norgibberell-16-en-7, 19-dioic acid, 7, 19-dimethyl ester) which is a new compound was synthesied from gibberellin A3 by ten steps. At the same time, the other three new compounds were also prepared. The structures were assigned by a combination of  ̄1H,  ̄(13)C-n. m. r. and mass spectroscopy.
- 【文献出处】 北京轻工业学院学报 ,JOURNAL OF BEIJING INSTITOTE OF LIGHT INDUSRY , 编辑部邮箱 ,1996年01期
- 【分类号】O624.5
- 【下载频次】52