【摘要】 单锂化Ｎ，Ｎ－二甲氨甲基二茂铁与二丁基二氯化锡反应生成一个锡原子桥连两个二茂铁基的有机锡化合物。此化合物与过量的碘甲烷作用生成其季铵盐，使此盐分别与亲核试剂甲醇钠、苄胺及六氢吡啶反应得到相应的三个新有机锡二茂铁衍生物，其结构通过核磁共振谱、质谱、元素分析和红外光谱得到了确证。更多还原

【Abstract】 Dimethylaminomethylferrocene was lithiated to the monolithiated product, with dibutyl which was treated in situ with dibutyl dichlorotin to form bis (2-(dimethyl aminomethyl)ferrocenyl) dibutyl-tin (Ⅰ). It then reacted with an excess of methyL iodide to produce methiodide (Ⅱ). The methiodide was treated subsequently to undergo nucleopnilic substitution respectively with sodium methoxide, benzylamine and piperidine, producing three corresponding new organotin derivatives of ferrocene(Ⅴ),(Ⅵ) and (Ⅶ). Their structures were confirmed by elemental analysis, IR, 1H-NMR and MS spectra. The 13C-NMR of (Ⅰ) was also performed.更多还原