【摘要】 首次报道了金属卟啉对phIO温和氧化环己醇反应的催化作用．研究结果表明：金属卟啉种类对反应产率有显著影响．不同金属卟啉催化下，反应产率次序为：TPPMnCI＞[TPPMn]2O＞[TPPFe]2O＞TPPFeCI＞TPPC0.phIO的量及其投料方式对反应产率有不同程度的影响．TPPC0与配体吡啶用量比例对反应也有影响．更多还原

【Abstract】 This paper first reported catalysis of metalloporphyrins for the mild oxidation of cyclohexanol with PhIO. The results showed that the pattern of metalloporphyrins greatly affected the reaction yields. There were following order of the reaction yields when different metalloporphyrins were used as catalysts: TPPMnCI >[TPPMn]2 O> [TPPFe]2O > TPPFeCI > TPPCo. The quantities and the put methods of PhIO could affect the reaction yields to varying degrees. The ratio of TPPCo to axial ligand pyridine affected the reaction, too.更多还原