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从α-蒎烯合成紫苏糖的研究

STUDIES ON SYNTHESIS OF FERILLARTINE FROM α-PINENE

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【作者】 郑延华卢礼灿

【Author】 Zheng Yinhua; Lu Lican (Department of Chemistry Xiangtan University, Xiangtan, 411105,China)

【机构】 湘潭大学化学系

【摘要】 紫苏糖又名紫苏亭,是一种高甜、低热的优质甜味剂,可作为饮料、糕点、烟草、牙膏和药物等的甜味剂和防腐剂,以及作为保健食品的添加剂.本文介绍了从α-蒎烯出发经二氧化硒选择性氧化、铜-锌催化异构化和肟化,合成紫苏糖的详细情况,探讨了各种因素对反应的影响.

【Abstract】 Using α-pinene as raw materials, the perillarine can be preparedb by selective oxidation with selenium dioxide, isomerization with copper-zinc catalyst under reduced pressure and oximation. It is a fine sweetener to possess high sweentness and low caloricity.In this paper, affections of the reaction conditions on yield were studied and optimum condition were given. In the synthesis of myrtenal, we used vanadium pentoxide as calatyst. In the catalytic ismerization of myrtnal, we used nitrogen as protectyve gas, The sum yield is raised fron 26% to 45%.

  • 【文献出处】 湘潭大学自然科学学报 ,NATURAL SCIENCE JOURNAL OF XIANGTAN UNIVERSITY , 编辑部邮箱 ,1995年01期
  • 【分类号】TQ281
  • 【被引频次】12
  • 【下载频次】165
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