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聚2,5-二甲氧基苯胺薄膜电极对儿茶酚的电催化作用
ELECTROCATALYTIC EFFECT OF POLY(2,5-DIMETHOXYANILINE)FILM ELECTRODES ON PYROCATECHOL
【摘要】 研究了电化学方法制备的聚2,5-二甲氧基苯胺薄膜电极(P25DMAn/Pt)对水溶液中儿茶酚的电催化作用,以及影响催化作用的主要因素,结果表明,在酸性较强的水溶液中,在较充的浓度范围内(儿茶酚的浓度为1×10 ̄-1~5×10 ̄-5mol/L)均有很好的电催化作用,催化电流与儿茶酚浓度呈良好的线性关系。
【Abstract】 Poly(2,5- dimethoxyaniline)film was synthesized with the method of electropolymerzation.Instrong acidic solution,the redox reaction of pyrocatechol could well be catalyzed by poly(2,5-dimethoxyaniline)film electrode in a wide range of pyrocatechol concentration.Some important fac-tors which affect electrocatalytic reaction of pyrocatechol at poly(2,5-dimethoxyaniline)film elec-trodes were discussed.The catalytic limiting currents were proportional to concentration of pyrocatecholin the range of l×10 ̄-1~5×10 ̄-5mo1/L,and poly(2,5-dimethoxyaniline)was very stable.
【Key words】 Poly(2,5-dimethoxyaniline); electrocatalytic reaction; pyrocatechol; conducting polymer;
- 【文献出处】 西南师范大学学报(自然科学版) ,JOURNALOF SOUTHWEST CHINA NORMAL UNIVERSITY(NATURAL SCIENCE) , 编辑部邮箱 ,1995年05期
- 【分类号】O643.3
- 【被引频次】1
- 【下载频次】60