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相转移催化法合成1,4-苯二氧基二乙酸及其衍生物
Phase transfer catalyzed synthesis of 1,4-phenylenedioxydiacetic acid and it’s derivatives
【摘要】 合成了1,4-苯二氧基二乙酸及其衍生物─—1,4-苯二氧基二乙酸、1,4-苯二氧基二乙酰氯、1,4-苯二氧基二乙酸二苯酚酯、1,4-苯二氧基二乙酰二苯胺、N,N-1,4-苯二氧基二乙酰基-N',N'-二苯氧基乙酰基二肼,合成反应采用了相转移催化技术,提高了产率,预计合成的化合物是一类新型的具有双活性中心的植物生长调节剂.
【Abstract】 phenylcnedioxydiacetic acid and its dcrivatives 1,4-phenylenedioxydiacetyl chloride,diphenyl 1,4-phenyldioxydiacetate,1,4-phenylenedioxydiacctanilide and N,N-1,4-phenylenedioxy-diacetyl-N’,N’-di(phenyloxyacetyl)hydrazide are synthesized in high yield by means of phase transfercatalysis. It is demonstrated that the synthesized cornpounds are a new-type plant-growth regulators withtwo active centre.
【关键词】 1;
4-苯二氧基二乙酸及其衍生物;
相转移催化;
植物生长调节剂;
【Key words】 phenylenedioxydiacetic acid and its derivatives; phase transfer catalysis; plant-growthregulator;
【Key words】 phenylenedioxydiacetic acid and its derivatives; phase transfer catalysis; plant-growthregulator;
- 【文献出处】 西北师范大学学报(自然科学版) ,JOURNAL OF NORTHWEST NORMAL UNIVERSITY(NATURAL SCIENCE EDITION) , 编辑部邮箱 ,1995年02期
- 【分类号】TQ452.6
- 【被引频次】11
- 【下载频次】152