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N-取代吩噻嗪和DDQ的电荷转移络合作用
Charge Transfer Complexation of N-substituted Phenothiazines with DDQ
【Abstract】 The charge transfer complexes (CTC) formed from N-substituted phenothiazines with 2,3-dichloro-5,6-dicyanobenzoquione (DDQ ) in 1,2-dichloroethane were studied spectrophotometrically. The CT spectra, ionization potentials of donor and the thermodynamic data (K, △H,△S) of CTC were determined. The results show that the charge donation of N-substituted phenothiazines is fairly strong and depends on the polarity of the substituent.
【关键词】 吩噻嗪;
2,3-二氯-5,6-二氰基苯醌(DDQ);
电荷转移络合物;
电离势;
【Key words】 Phenothiazines; 2; 3-dichloro-5; 6-dicyanobenzoquinone (DDQ); Charge transfer complex; Ionization potential;
【Key words】 Phenothiazines; 2; 3-dichloro-5; 6-dicyanobenzoquinone (DDQ); Charge transfer complex; Ionization potential;
【基金】 国家自然科学基金
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1995年10期
- 【分类号】O626
- 【被引频次】2
- 【下载频次】91