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N-取代吩噻嗪和DDQ的电荷转移络合作用

Charge Transfer Complexation of N-substituted Phenothiazines with DDQ

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【作者】 英柏宁吴国湘

【Author】 Ying Baining; Wu Guoxiang (Department of Chemistry. Zhongshan University Guangzhou 510275)

【机构】 中山大学化学系!广州510275

【Abstract】 The charge transfer complexes (CTC) formed from N-substituted phenothiazines with 2,3-dichloro-5,6-dicyanobenzoquione (DDQ ) in 1,2-dichloroethane were studied spectrophotometrically. The CT spectra, ionization potentials of donor and the thermodynamic data (K, △H,△S) of CTC were determined. The results show that the charge donation of N-substituted phenothiazines is fairly strong and depends on the polarity of the substituent.

【基金】 国家自然科学基金
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1995年10期
  • 【分类号】O626
  • 【被引频次】2
  • 【下载频次】91
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