节点文献
在超声分子束条件下Mn2（CO）10的多光子电离解离
Multiphoton Ionization and Dissociation of Mn2（CO）10 in a Supersonic Molecular Beam
【Abstract】 The multiphoton ionization and dissociation of Mn2(CO)10 in a supersonicmoleclar beam is investigated with a XeCl excimer laser (308nm) and a tunable dye laser(430 ~ 448nm). The main fragment ions detected by a time-of-fligh mass spectrometer include Mn+, Mn(CO)x+(x<5), Mn2(CO)y+ (y<9) and the parent molecular ionMn2(CO)10+. Additionally, metal cluster ions Mni+(i=2,3,4) and metal carbonyl clusterions Mn3(CO)9,10+ and Mn4(CO)10+ are also detected. The Mn+ ion might be producedvia a sequential photodissociation to form Mn atorns first and followed by a nonresonantor resonant enhanced multiphoton ionization of Mn atoms. The mechanism of the laserinduced multiphoton ionization and dissociation is discussed.
【关键词】 Mn2（CO）10；
多光子解离电离；
反应动力学；
【Key words】 Mn2（CO）10； Multiphoton ionization/dissociation； Chemical kinetics；
【Key words】 Mn2（CO）10； Multiphoton ionization/dissociation； Chemical kinetics；
【基金】 国家自然科学基金
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,1995年02期
- 【分类号】O614.711
- 【被引频次】5
- 【下载频次】41