【摘要】 本文合成和表征了一种新的标题大环Ｌ和它的配合物［ＮａＣｌＯ４·Ｌ］２．配合物的晶体结构表明，两Ｌ分别与两钠原子直接配位，并通过两高氯酸根的两μ２－Ｏ桥形成了夹心型双聚结构单元．更多还原

【Abstract】 A new title macrocycle L and its complex [NaClO4·L]2 have been synthesized and characterized.The crystal structure of the complex shows that two L direct coordinate two sodium atoms,rcspectively,and two perchloraec μ2-O bridges make them form a sandwich dimeric structure unit.更多还原