【摘要】 本文设计了两种不同合成路线，分别制得了相应的铜（Ⅱ）／铁（Ⅲ）Ｓａｌｅｎ双核配合物［Ｓａｌｅｎ代表Ｎ，Ｎ＇－亚乙基双（水杨醛缩亚胺）二价酸根］．通过对这两种产物的元素分析、红外光谱、电子光谱、磁化率及质谱的测定，确定它们属于同一种双核配合物，化学组成为ＣｕＦｅ（Ｓａｌｅｎ）Ｃｌ３·１／２Ｓ（Ｓ＝ＣＨＣｌ３或ＣＨＣｌ２），并对它们的结构进行了讨论．更多还原

【Abstract】 In this paper two different synthetic methods for the Cu(Ⅱ ) / Fe(Ⅲ ) Salen complex were described,and the same binuclear complexes CuFe(Salen)Cl3·1 / 2S were obtained,(where Salen stands for the dianion of N,N’-ethylene-his(salicylidcncdi and S dcnotCs CHCl3 or CH2Cl2),as confirmed by clemental analysis,infrared,electronic and mass spectra,and magnetic susceptibility measurements.Based on the information as mentioned above,a tantative dimerie structUre was suggested.更多还原