【摘要】 石墨－ＡｌＣｌ_３的熔盐电解合成及电化学性能房艳，康永峰，葛芹，余世英（中国科学院青海盐湖研究所，西宁８１０００８）关键词：石墨插入化合物，电解合成，阴极材料自六十年代以来，随着石里扬人化合物（ＧＩＣ）材料在超导体、催化剂、高能量密度电池和有机反应试?..更多还原

【Abstract】 he graphite intercalation compound AlCl3-GIC has been prepared by electrolytic method in MAlCl4 melt salt with graphite anode stainless steel cathode. The electrode reaction equation in the electrolytic process can be written as. CnAlCl3+1 /2Cl2+M,where the number n of carbon atom is inversely proportional to quantity of electricity passed （n = 23.9￣14.2）. Mean composition and structure of the electrolytic products at various condition were measured by chemical analysis and X-ray powder diffraction. The possibility and the behavior of AlCl3-GIC as positive electrodc of Li cell were investigated by typical voltammetric curve and discharge test in 1 .5mol. 1（-1） LiAlCl₄-propylene carbonate（PC）.更多还原