节点文献
铁(Ⅲ)-5-硝基-邻菲啰啉配合物光还原作用的研究
On the Photo-reduction of Iron(Ⅲ)-5-nitro-1,10-phenanthroline Complex
【摘要】 无色的铁(Ⅲ)-5-硝基-邻菲 啉配合物在紫外光照射下发生光还原反应,生成红色的铁(Ⅱ)-5-硝基-邻菲 啉。实验证明,各种羧酸及表面活性剂均能影响上述反应,并对其机理作初步探讨。
【Abstract】 Upon the irradiation of ultraviolet light, a red ferrous complex with 5-nitro-1,10-phenanthroline is formed by the photo-reduction of the corresponding colourless ferric complex.Experiments showed that the photoreaction is affected by the solution pH value and by the presence of carboxylic acids and surface-active agents.The reaction mechanism was preliminarily discussed.
【基金】 国家自然科学基金
- 【文献出处】 分析测试学报 ,JOURNAL OF INSTRUMENTAL ANALYSIS , 编辑部邮箱 ,1995年03期
- 【分类号】O621.254.2
- 【下载频次】47