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由混合二元酸制取过氧化戊二酸
Preparation of Peroxide Of Glutaric Acid From Mixture of Dicarboxylic Acids
【摘要】 详细研究利用生产己二酸副产的混合二元酸制取过氧化戌二酸的工艺流程和操作条件。试验采用乙酸酐做脱水剂,由混合二无酸制取戊二酸酐,再用过氧化氢氧化制得过氧化戊二酸。在试验基础上,确定出了备步反应及其产物分离的工艺条件。
【Abstract】 A process and related operating conditions were studied in detail for preparing glutaricacid peroxide from a mixture of dicarboxylic acids,which is a by-product in the manufact-ure of adipic acid.Glutaric anhydride was first prepared With acetic anhydride as dehydrating agent, and hydrogen peroxide was used as oxidant for the preparation of glutaric acidperoxide. Optimal operating conditions for each reaction and separation of the products weredetermined.
【关键词】 二元酸;
戊二酸;
戊二酸酐;
过氧化戊二酸;
引发剂;
【Key words】 dicarboxylic acids; glutaric acid; glutaric auhydride; peroxide of glutaric acid; initiator;
【Key words】 dicarboxylic acids; glutaric acid; glutaric auhydride; peroxide of glutaric acid; initiator;
- 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,1995年02期
- 【分类号】TQ225.145
- 【被引频次】18
- 【下载频次】204