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高分子冠醚的合成及其色谱性能研究
STUDY ON CHROMATOGRAPHIC CHARACTERISTICS OF THE CROWN ETHER POLYMER SYNTHESIZED AS A STATIONARY PHASE FOR CAPILLARY GAS CHROMATOGRAPHY
【摘要】 本文合成了一种新型聚硅氧烷侧链全氧冠醚(丙烷氧甲基15—冠—5),并将其涂清在未经处理的弹性石英管柱上,其柱效较高,使用温度范围较宽,热稳定性和选择性较好.研究了固定液对样品的分离机理.
【Abstract】 A new kind of crown ether ,propvloxymethyl - 15 -crown-5 sidechain polysiloxane was synthesized and coated on capillary columns. Its chromatographic characteristics including column efficiency, allowable operating temperature range, thermal stability , polarity and selectivity were studied,and its separation mechanism was discussed.
【关键词】 固定相;
冠醚;
石英毛细管柱;
气相色谱;
【Key words】 Stationary phase; Crown ether; Quartz glass capillary; Gas chromatography.;
【Key words】 Stationary phase; Crown ether; Quartz glass capillary; Gas chromatography.;
【基金】 国家自然科学基金资助
- 【文献出处】 湖北教育学院学报 , 编辑部邮箱 ,1995年04期
- 【分类号】O633
- 【被引频次】3
- 【下载频次】37