【摘要】 乙二胺，１．２－丙二胺，邻苯二胺和间苯二胺分别与α－取代二茂铁甲基氟硼酸盐反应，得到九种新的二茂铁二胺配体化合物，并以Ｎ，Ｎ＇－双［二（二茂铁基）甲基］乙二胺为配体，制得了五种二价金属［Ｚｎ（Ⅱ），Ｃｕ（Ⅱ），Ｆｅ（Ⅱ），Ｃｏ（Ⅱ）和Ｎｉ（Ⅱ）］配合物更多还原

【Abstract】 ine ferrocene derivatives of diamines were synthesized by the reaction of fluorborate of α-subsituted ferrocenyl carbinol FcC（R₁R₂）OH（R₁ =Fc,C₆H₅;R₂=H,C₆H₅）with ethylenediamine,1,2-diaminopropane,O-phenylenediamine and m-phenylenediamine respectively. Five transitionmetal(Cu（Ⅱ）,Zn（Ⅱ）,Fe（Ⅱ）,Co（Ⅱ）,Ni（Ⅱ）]complexes of N,N’-di（bisferrocenylmethyl）ethylenediamine are prepared. All of these new compounds and complexes are characterized by el-emental analysis,IR and ￣1 HNMR spectra.更多还原