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扰流色谱的研究──利用扰流色谱测定气体扩散系数
A STUDY OF FLOW PERTURBATION GAS CHROMATOGRAPHY THE MEASUREMENTS OF THE DIFFUSION COEFFICIENTS
【摘要】 本文分别用返流色谱法和R(F)峰法测定了不同温度下有机气体乙烯、丙烯、乙炔在氮气流中的扩散系数和苯、环已烷、乙醇、乙酸乙酯等有机蒸气的扩散系数,讨论了各种操作参量对测量精度的影响,大量测量结果表明,返流色谱法的平均偏差为3.32%,而R(F)峰法为4.49%。
【Abstract】 The diffusion coefficients is determined by flow perturbation GC in this paper,Values of diffusios coefficients determined by the reversed-flow method are closer to the theoretiques .In this paper, the variation of the diffusion coefficients for the differential temperatures the carrier gas ffow-rate and other factors was studied.
- 【文献出处】 南开大学学报(自然科学版) ,ACTA SCIENTIARUM NATURALIUM UNIVERSITATIS NANKAIENSIS , 编辑部邮箱 ,1995年02期
- 【分类号】O657.7
- 【被引频次】1
- 【下载频次】103