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硫酸溶液中铬酸钾在不锈钢表面的电化学还原行为
ELECTROCHEMICAL REDUCTION BEHAVIOR OF POTASSIUM CHROMATE ON SURFACE OF STAINLESS STEEL IN SULFURIC ACID SOLUTIONS
【摘要】 在硫酸溶液中对不锈钢进行阳极极化曲线的测定表明,铬酸钾在不锈钢表面的还原反应受铬酸根离子在溶液中的扩散步骤所控制,且在不锈钢致钝的电位区间内达到了极限扩散。对不锈钢进行电位滴定的实验结果也证实了铬酸根离子的这一还原行为。
【Abstract】 In 0.50mol/l. H2SO4 solutions(30℃,deaerated ), anodic polarization curves of stainless steel indicated that reduction of K2CrO4 on the surface of stainless steel was wholly controlled by diffusion step of CrO42- at passivation polential of stainless steel. Critical passivation concentrations of K2CrO4 for stainless steel determined by potentiomctric titration were consistent with values calculated according to parameters of POlarization curves of stainless sted.
【关键词】 铬酸钾;
扩散控制;
电化学还原;
不锈钢;
致钝;
【Key words】 potassium chromate; diffusion controll; electrochemical reduction; stainless steel; passivation;
【Key words】 potassium chromate; diffusion controll; electrochemical reduction; stainless steel; passivation;
【基金】 国家自然科学基金
- 【文献出处】 南京化工大学学报 ,JOURNAL OF NANJING UNIVERSITY OF CHEMICAL TECHNOLOGY , 编辑部邮箱 ,1995年S1期
- 【分类号】TG174.42
- 【被引频次】2
- 【下载频次】49