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加氢作用对煤沥青性能的影响

HYDROGENATION EFFECTS ON PITCH PROPERTIES

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【作者】 吕永康王志忠

【Author】 Lu Yongkang and Wang Zhizhong(Taiyuan University of Technology,030024 Taiyuan)

【机构】 太原工业大学

【摘要】 研究了煤沥青溶剂加氢前后物化性质与分子结构的变化,探讨了加氢反应机理和氢转移反应对缩聚沥青可纺性以及炭纤维性能的影响。结果表明:THQ是良好的供氢溶剂,煤沥青与THQ反应后,增加了沥青分子中的环烷结构,使其流变性和可纺性得到了明显的改善,为后处理过程制得高性能炭纤维奠定了基础。

【Abstract】 In this paper,properties and molecular structure of pitch and hy-drogenated pitch were investigated.Mechanism of hydrogenation and effect of hy-drogen-transfer reaction on spinnability were also studied.It is shown that THQ is a good H-donor solvent,hydrogenated pitch displays a better fluidity and spinnabi-lity,and contains naphthenic rings.Hydrogenated pitch provides the basis for pro-ducing performance carbon fiber.

【关键词】 煤沥青加氢炭纤维
【Key words】 coal tar pitchhydrogenationcarbon fiber
【基金】 国家自然科学基金
  • 【分类号】TQ522.65
  • 【被引频次】8
  • 【下载频次】195
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