【摘要】 用辛可芬酰肼与异硫氰酸酯在无水乙醇中反应,合成了新配体1—辛可芬酰基—4—苯基氨基硫脲。并用此配体与金属醋酸盐在乙醇溶液中回流4h,得到六个二价金属(Cu、Ni、Cd、Zn、Co、Pb)新配合物,产率在62％～73％之间。经元素分析,摩尔电导,红外光谱,HNMR和热重分析可确定这些配合物为四配位聚合态结构。它们的生物活性试验正在进行中。更多还原

【Abstract】 A new ligand, 1-Cinchophenoyl-4-phenylthiosemicarbazide has been synthesized by the reaction of phenylisothiocyanate with cinchophenoyl hydrazide in absolute ethanol. Its divalent metal (Cu,Ni,Cd,Zn, Co,Pb)complexes have been prepared by refluxing the ligand and the hydrated metal acetate in ethanol for 4hrs,yield 62-73%. The complexes have been characterized by elemental analyses,molar conductivites, IR,1HNMR,TGA.更多还原