节点文献
钌的硫脲比色测定
SPECTROPHOTOMETRIC DETERMINATION OF RUTHENIUM WITH THIOUREA
【摘要】 本文讨论了钌同硫脲的显色反应,在不经分离的条件下,将Ru还原Ru ̄Ⅱ,Ru ̄Ⅱ与硫脲生成蓝色,λ_最大=635nm,在0-300μg/ml范围内呈线性关系。本法适宜测定含Ru量较高钌的渣及其选矿成品。
【Abstract】 The determination of ruthenium used to be determined through distillation,fractiona-tion and enrichment. But the authors improve the method which ruthenium is reduced intoRu ̄Ⅱ by reductant. Ru ̄Ⅱ with thiourea forms a blue complex. λ_max=635nm. In the range of 0-300μg/ml,the content of ruthenium obeys Beer′s Law. This method has been applied to thedetermination of Ru in ruthenium slag.
- 【文献出处】 辽宁地质 ,LIAONING GEOLOGY , 编辑部邮箱 ,1995年02期
- 【分类号】O614.821
- 【被引频次】1
- 【下载频次】69