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含水氯化物体系中金和银的相对溶解度测定
RELATIVE SOLUBILITIES OF Au AND Ag IN THE AQUEOUS CHLORIDE SYSTEM
【摘要】 文章叙述了用Au-Ag合金测定Au和Ag溶解度及讨论Au的热液行为的意义和方法。实验结果指出:在300℃,fo2在10-35~10-14间,∑Cl-=3.0mol/kg和有含银矿物存在时,Au-Ag系列与含水氯化物热液反应,Au-Ag系列中纯AU的溶解度最高,中间组分的溶解度随XAu的增加而升高,而银的溶解度随XAg的变化不明显,但随∑Cl-浓度的增加而升高,在含银相存在时,金和银总是趋向于形成富金的Au-Ag系列。
【Abstract】 This paper deals with the method to measure the relative solubilities of Au and Ag by using Au-Ag alloy and discuss the behavior of Au in hydrothermal solutions. Experimental results show that at 300℃ and fo1 = 10 -15 ~ 10-14, ∑Cl-=3. 0mol/kg and that when the Au-Ag series reacts with aqueous chloride hydrothermal solutions in the presence of Ag-bearing minerals, the solubili-ty of pure Au in the Au-Ag series is highest, that of the intermediate cmoponents tends to increase with increasing XAu,and that of Ag displays unremarkable variation with XAg.,but tends to in-crease with increasing concentration of ∑C-. In the presence of Ag-bearing phase, the general tendency of Au and Ag is to form the Au-rich Au-Ag series.
- 【文献出处】 矿物学报 ,Acta Mineralogica Sinica , 编辑部邮箱 ,1995年02期
- 【分类号】P59
- 【下载频次】31