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铸铁铬硅共渗渗层组织特征及形成机制

Microstructure Feature and Forming Mechanism of Chromized-Siliconized Layer for Cast Iron

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【作者】 张黔李朝志李正刚胡平

【Author】 Zhang Qian; Li Chaozhi; Li Zhenggang; Hu Ping(Wuhan University of Hydraulic and Electric Engineering)

【机构】 武汉水利电力大学

【摘要】 采用固气法对铸铁铬硅共渗渗层的组织特征和形成机制进行了分析和探讨。显微分析表明,渗层由a相和Cr_7C_3、Cr_23C_6等碳化物组成,其外表面富集的铬含量可达30%以上,不含石墨。渗层下面为含大量珠光体的过渡区,靠近表面的渗层里,可观察到包围石墨的白亮环区。该环区很可能是因共渗过程中Cr、Si原子在石墨周围局部聚集而形成的。保温时间延长,环内石墨消失,但仍保留环区特征。这种组织结构提高了铸铁的抗蚀能力及抗高温氧化能力。

【Abstract】 The microstructure feature and its forming mechanism of chromized-siliconized layer for cast iron by solid-gas diffusion methed were in vestigated,The microanalysis showed that the surface layer of chromized-siliconized specimen consists of a phase and some carbides Cr7C3 and Cr23C6.The chromium content in the area near surface of spocimen is more than 3 0 wt%and graphite was not obeerved.Under the laver there is a transition region,contain ing large amount of porlite ,where some a phase zone,surrounding graphite,was fou nded; Forming of a phase zone likely is caused by local gathering of atoms of Cr and Si close to the srapmte,With prolonged holding at the temperature for chromizing-siliconizing,undissolved graphite containing in the phase zone,can be dissolved in austenite,but its feature will be remained after cooling of specimen,This microstructure in the surface layer of cast iron after chromizing-siliconizing greatly im proves its corrosion resistance and high temperature oxidation resistance.

  • 【文献出处】 金属热处理学报 ,TRANSACTIONS OF METAL HEAT TREATMENT , 编辑部邮箱 ,1995年03期
  • 【分类号】TG156.8
  • 【被引频次】1
  • 【下载频次】58
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