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基团转移聚合反应分子量分布
Molecular Weight Distfibmions of Methyl Methacrylate by Group Transfer Polymerization
【摘要】 合成了基团转移聚合反应引发剂亚磷酸二乙三甲硅酯,用该引发剂对甲基丙烯酸甲酯作了聚合反应分子量研究,并用从理论上计算得到的分子量与实验值作了比较。
【Abstract】 This paper reports the syntheses of initiator Me3 SiOP(EtO)2 and catalyst Et4NHF2.Theaverage molecular weights for polymethylmethacrylate are calculated theoretically and compared withthat obtained by GPC,it’s;molecular weight distribution is narrow(d=1.04),which is of importancein coatings and plastics industries.
【关键词】 基团转移聚合;
聚甲基丙烯酸甲酯;
平均分子量;
分子量分布;
【Key words】 group transfer polymerization; polymethylmethacrylate; average molecular weight; molecular weight distribution;
【Key words】 group transfer polymerization; polymethylmethacrylate; average molecular weight; molecular weight distribution;
- 【文献出处】 吉林大学自然科学学报 ,ACTA SCIENTIARIUM NATURALIUM UNIVERSITATIS JILINENSIS , 编辑部邮箱 ,1995年03期
- 【分类号】O631.5
- 【下载频次】146