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Fe/ZrO2气凝胶超细粒子催化剂的XAFS研究

XAFS Study of Fe/ ZrO2 Aerogel Ultrafine Particle Catalysts

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【作者】 胡天斗谢亚宁黄达贤陈贤能靳亚兰相宏伟钟炳彭少逸

【Author】 HU Tian-Dou XIANG Hong-Wei XIE Ya-Ning HUANG Da-XianCHEN Xian-Neng JIN Ya-Lan(Synchrotron Radiation Laboratory, Institute of High Energy Physics.The Chinese Academy of Sciences, Beijing, 100039)ZHONG Bing PENG Shao-Yi(Institute of Coal Chemistry, The Chinese Academy of Sciences, Taiyuan, 030001)

【机构】 中国科学院高能物理所同步辐射室中国科学院山西煤炭化学所中国科学院山西煤炭化学研究所中国科学院山西煤炭化学研究所 北京100039北京100039太原030001太原030001

【摘要】 采用XAFS方法对Fe2/ZrO2气凝胶超细粒子催化剂中Fe的近邻结构进行研究.随着催化剂颗粒减小,Fe/ZrO2远程结构逐渐无序,Fe最近邻Fe-O配位数不变,Fe-O键长略有下降,次近邻Fe-O配位数和键长均减小,对于高配位层,配位数下降更快,Fe的配位环境的影响与催化剂活性和选择性的规律有较好的关联.

【Abstract】 A series of Fe / ZrO2 catalysts with different particle size has been prepared by the supercritical fluid drying and conventional impregnation methods. The neighboring coordinative environment of iron in these catalysts was investigated by XAFS. The results show that as the particle size of Fe/ ZrO2 catalysts is decreased, their structure is disorder gradually, the coordination number of the first Fe-O shell does not change and their Fe-O bond length has a litter shrink, The coordination number and bond length of the second Fe-O shell are decreased, and coordination number of higher coordination shell decreases very quickly. The correlation between the XAFS results and the activity and selectivity of these catalysts was obtained.

【关键词】 Fe/ZrO2催化剂XAFS气凝胶超细粒子
  • 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,1995年11期
  • 【分类号】O643.3
  • 【被引频次】3
  • 【下载频次】97
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