【摘要】 在气相条件下研究了C₆₀与环己烷及环己烯的离子-分子反应.C₆₀可与上述体系中多种离子发生反应,生成相应的加合离子,表现出C₆₀化学性质的活泼性和多样性.C₆₀与C₄H₇⁺和C₅H₇⁺离子反应可能生成[2+4]环加成的加合离子.更多还原

【Abstract】 The DCI MS of C60 with the reactions of gaseous cyclohexane and cyclohexene have been studied. Several kinds reactions of C60 have been observed. The results show that the gas-phase C60 has very active chemical properties. The adduct ions of [C60C4H7]+ and [C60C5H7] + may be formed by [2+4] cycloaddition where one of double bonds of C60 acted as a dienophilic unit.更多还原