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5-Br-PADAP一阶导数光度法同时测定钴和镍的研究

Study on the simultaneous determination of cobalt and nickel with 5-Br-PADAP by first-order derivative spectra

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【作者】 张书圣王云东江淑芙

【Author】 Zhang Shusheng;Wang Yundong;Jiang Shufu (Department of Applied Chemistry, Qingdao Institute of Chemical Technology, Qingdao 266042)

【机构】 青岛化工学院应化系

【摘要】 本文研究了5-Br-PADAP与钴、镍反应的导数行为,利用一阶导数光度法同时测定钴和镍的新方法。用所建立的方法对化学试剂中的钴和镍的含量进行了同时测定,结果令人满意。

【Abstract】 The method is based on the colour reaction of Co(Ⅱ) and Ni(Ⅱ) with 5-Br-PADAP in weakly alkaline medium. The first derivative spectrophotometric method can resolve the over lapping absorption spectra of Co(Ⅱ) and Ni(Ⅱ). The developed method proves satisfactory for the simultaneous determinatian of micro amounts of Co and Ni in synthetic samples.Satisfactory results were obtained in the determination of trace cobalt and nickel in some chemical reagents.

【关键词】 一阶导数光度法
【Key words】 CobaltNickelfirst derivative spectrophotometry
【基金】 国家自然科学基金
  • 【分类号】O614.81
  • 【被引频次】6
  • 【下载频次】35
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