【摘要】 以Ｃｅ￣（４＋）／Ｃｅ￣（３＋）为氧化还原体系，以硫酸为支持电解质，采用槽内法研究了苄醇的选择性间接电氧化。得出最佳电解条件：电流密度，０．１Ａ／２０ｃｍ￣２；亚铈与反应物当量比，１：６；硫酸浓度，３ｍｏｌ／Ｌ；通过电量，２Ｆ／ｍｏｌ（Ｆ为理论电量）。在最佳电解条件下，反应产物为苯甲醛，产率高达９６％，不发生深度氧化。阳极液循环１０次以上，对反应产率无影响。反应中Ｃｅ￣（４＋）只起电子传递作用，反应仅消耗电能，因此此法十分经济，且无污染。更多还原

【Abstract】 This paper describes the indirect electrooxidation of benzalcohol in a Ce( Ⅳ)/Ce(Ⅲ) redoxsystem , using sulfuric aciti as the support electrolyte. The optimum conditions for the electrolysis are: cur-rent density, 0. 1A/20cm￣2; ratio between cerous nitrate and reactids matertal, 1: 6,concentration of sul-furic acid, 3mol/L; electroquantity, 2F/mol. Under the optimum condition, the yield of the reactiontouches to 96% without deep oxitiation. The eathode solution can be reused for more than ten times, andno effect was observed on the yield of the product. Therefore , this electrooxitiation method is a economicaland pollution-free procedure , in which only electric energy is consumed.更多还原