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单斜辉石固溶体CaMgSi2O6-NaAlSi2O6的临界相转变研究
INVESTIGATION OF THE CRITICAL PHASE TRANSFORMATION OF CLINOPYROXENE ON THE JOINT CaMgSi2O6-NaAlSi2O6
【摘要】 对固溶体CaMgSi_2O_6-NaAlSi_2O_6相转变过程中的临界压力p和临界温度T之间的关系进行了研究,得到p与T之间为一线性关系:p=1.54×10 ̄(-2)T-14.3(GPa)。另外,在临界条件下,对合成的单斜辉石的微观结构进行了SEM观察,发现在较高的临界压力和临界温度下,样品晶粒粗壮、紧密,并且主要沿(001)面生长成纤维状。控制一定的过冷却度使其在成核区停留一段时间之后升温到生长区,样品的SEM观察结果显示与上述结论一致。
【Abstract】 The critical pressure and critical temperature in the phase transformation of clinopyroxene solid so-lution CaMgSi2O6(diopside,Di)-NaAlSi2O6(jadeite,Jd)from glass were investigated. The equation of phasetransformation of Di0.4-Jd0.6 is given as follows:p=1.54×10 ̄(-2)T-14.3 (GPa).The penetrating fibrous grainsof Di-Jd are mainly grown along the direction of c-axis under the higher critical preessure and at the higher criti-cal temperature. At lower critical pressure and temperature the penetrating fibrous grains are shorter,looser anddisordered.
【Key words】 clinopyroxene; phase transformation; microstructure; high-pressure;
- 【文献出处】 硅酸盐学报 ,JOURNAL OF THE CHINESE CERAMIC SOCIETY , 编辑部邮箱 ,1995年04期
- 【分类号】TQ170.11
- 【下载频次】83