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色谱法测定几种芳烃在无水乙醇中的扩散系数
Measurement of Liquid Diffusion Coefficients for Aromatic Hydrocarbon in Ethanol by the Chromatographic Broadening Technique
【摘要】 建立了色谱法扩散系数测定装置。在常压下,298.2K~333.2K的范围内测定了苯、甲苯、对二甲苯、邻二甲苯、乙基苯、均三甲苯、萘、菲、蒽和联苯等十种芳烃在无水乙醇中的无限稀释扩散系数,共40点,用Wilke-Chang方程进行了关联
【Abstract】 An apparatus for measuring the liquid diffusion coefficient by chromatographic broadening technique was established. Diffusion coefficients were measured for benzene, toluene, p-xylene, oxylene, ethylbenzene, 1, 3, 5-trimethylbenzene. naphthalene,phenanthrene, anthracene , biphenyl in ethanol from 298. 2K~333.2K. The data were correlated with Wilke-Chang equation ,and the average deviation of correlation is 3. 80%。
【关键词】 扩散系数;
色谱法;
乙醇;
【Key words】 Diffusion coefficient; Chromatographic broadening technique; Ethanol;
【Key words】 Diffusion coefficient; Chromatographic broadening technique; Ethanol;
- 【文献出处】 高校化学工程学报 ,JOURNAL OF CHEMICAL ENGINEERING OF CHINESE UNIVERSITIES , 编辑部邮箱 ,1995年01期
- 【分类号】O625.1
- 【被引频次】4
- 【下载频次】126