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碳硼烷衍生物对固体推进剂燃烧性能影响研究

Effects of Carborane Derivatives on the Combustion of Solid Propellants

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【作者】 单文刚孙铁刚张国东

【Author】 Shan Wengang;Sun Tiegang;Zhang Guodong (Xi’an Modern Chemistry Research Institute, 710061)

【机构】 西安近代化学研究所

【摘要】 研究了碳硼烷丙烯酸甲酯(CMP)对AP/NG和RDX/NG推进剂燃速的影响,结果表明,随CMP含量的增大,AP/NG推进剂燃速增大,压强指数呈下降趋势;在压强为8.0~10.0MPa范围内,CMP对提高RDX/NG推进剂的燃速作用最强,且随CMP含量增高,RDX/NG推进剂压强指数增大。CMP对AP和NG相变温度、熔融温度都有影响,并加速AP和RDX的分解。

【Abstract】 Effects of carboranyl methyl propionete (CMP) on the burning rate of AP/NG and RDX/NG propellants are investigated. The results indicate that the burning rate of propellants is greatly enhanced by the addition of CAP. With the increase of added CMP wt%, the burning rate of AP/NG increases and the pressure exponent decreases. The best catalysis of CMP on RDX/NG propellants appears under 8.0~10. 0MPa. The pressure exponent of RDX/NG propellants increases with the increase of CMP wt%. Both the temperature of AP phase transition and RDX melting and the decomposition of AP and RDX are affected by the addition of CMP.

  • 【文献出处】 固体火箭技术 ,JOURNAL OF SOLID ROCKET TECHNOLOGY , 编辑部邮箱 ,1995年03期
  • 【分类号】V435.12
  • 【被引频次】18
  • 【下载频次】307
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