【摘要】 二巯基嘧啶与ＣｌＯ_４^－在银电极上的共吸附王仲权，李五湖，任斌，田中群（厦门大学化学系厦门大学固体表面物理化学国家重点实验室厦门３６１００５）Ｃｏａｄｓｏｒｐｔｉｏｎｏｆ２－ＭｅｒｃａｐｔｏｐｙｄｍｉｄｉｎｅｗｉｔｈＣｌＯａｔＳｉｌｖｅｒＥｌｅｃｔｒ...更多还原

【Abstract】 Abstract 2-mercaptopyrimidine （2MP） has been used as an electroplatin addi-tive and metal corrosioninhibitor．Therefore，it is essential to understand the adsorption behaviour of 2MP at electrode surfaces through Raman spectroscop- ic studies．A preliminary study on 2MP coadsorbed with anion at silver elec-trodes has been carried out in our laboratory. By studying the electrochemical physically induced cotldsorption of 2MP and ClO，it has been shown that in more negative electrode potential region，2-MP is reduced as a new product that can even more preferable to induce the anion to coadsorbed at the siirface.Some interestin comparisosn will he presented based on two physically induced coadsorption svstems，i．e.TU＋anion and 2MP＋anion.更多还原