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热致液晶PEI与PES—C共混物的研究

Studies on the Blends of Thermotropic Liquid Crystalline Polymer PEI and PES-C

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【作者】 郑京桥王尚尔张宏放陈天禄莫志深

【Author】 Zheng Jingqiao;Wang Shanger;Zhang Hongfang;Chen Tianlu;Mo Zhishen (Polymer Physics Lahoratory, Changchun Inshtuts of Appiled Chemistory, Academia Sinica, Changchun 130022)

【机构】 中国科学院长春应用化学研究所

【摘要】 通过熔融共混,制备不同配比(2.5/97.5~75/25)的PEI/PES—C共混物,使用WAXD、DSC、锥板流变仪、力学性能测试、SEM等方法对共混物进行了研究。共混后强度、模量均有提高,在高剪切速率下,共混物的粘度有所降低。扫描电镜照片显示,共混物具有“皮芯”结构。

【Abstract】 lends of thermotropic liquid crystalline poly(ester-imide) (LCPEI) and an amorphous Phenolphthalein poly(ether-sulphone) (PES-C)were prepared by using small single screw extruder. The morphology and the mechanical properties were studied by WAXD,DSC,SEM, rheological experiment and mechanical test. The strength and modulus of the PEI / PES-C blends were increased and reached the maxmium at composition of 75% and 50% PEI respectively. The viscosity was significantly decreased with the addition of 10% LCPEI,thus the processing condition might be improved.SEM photographs showed that the blends possessed "core-shell" structure. The liquid crystalline polymer formed anisotropic fine fibers in the shell and spherical or elliptical domains in the core. They were all fairly dispersed into the PES-C matrix.

【基金】 国家自然科学基金
  • 【文献出处】 功能高分子学报 ,JOURNAL OF FUNCTIONAL POLYMERS , 编辑部邮箱 ,1995年03期
  • 【分类号】O753.2
  • 【被引频次】6
  • 【下载频次】79
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