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氯化聚丙烯热氧降解研究

STUDY ON THERMAL OXIDATIVE DEGRADATION PROCESS OF Cl-PP

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【作者】 张宜红朱诚身王经武汤克勇

【Author】 Zhang Yihong; Zhu Chengshen; Wang Jingwu; tang Keyong(Department of Material Engineering, Zhenzhou University, Zhengzhou)

【机构】 郑州大学材料工程系

【摘要】 用TG-DTG-DSC法研究了低氯化聚丙烯(Cl-PP),于空气中在不同升温速率β时的热氧降解过程,可为4步反应;随β增大,降解温度线性升高,失重率变化不大;结合反应热效应,探讨了反应机理。

【Abstract】 By using of TG-DTG-DSC, the thermal oxidative degradation process of Cl-PP in air at different heating rates have been studied. the process is four step reactions. With the increasing of heating rates, the degradational temperatures are raised linearly, but the change of degradational degrees are unnotable. The possible degradational mechanism of Cl-PP has been discussed according to the heating effect of reaction.

  • 【文献出处】 高分子材料科学与工程 ,POLYMERIC MATERIALS SCIENCE & CNGINEERING , 编辑部邮箱 ,1995年06期
  • 【分类号】TQ325.14
  • 【被引频次】9
  • 【下载频次】152
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