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碳笼烯的高分子化──苯乙烯-烯丙基胺共聚物与C60的反应

FULLERENE-FUNCTIONALIZED POLYMER──REACTION OF C60 WITH POLY (STYRENE-CO-ALLYLAMINE)

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【作者】 田慧洁周锡煌李福绵

【Author】 TIAN Huijie;ZHOU Xihuang;LI Fumian (Department of Chemistry. Reking University,Beijing 100871)

【机构】 北京大学化学系

【摘要】 碳笼烯的高分子化──苯乙烯-烯丙基胺共聚物与C_(60)的反应田慧洁,周锡煌,李福绵(北京大学化学系北京100871)关键词碳笼烯的高分子化,C_(60),苯乙烯-烯两基胺共聚物碳笼烯(fullerene)是因其具有特殊的功能性质m而颇受青睐的球簇分...

【Abstract】 Reaction of C60 with poly (styrene-co-allylamine)was studied by GPC, FT-IR and TGA methods.GPC traces demonstrated that the M.of reaction product increased and exhibited a broader molecular weight distribution.The strong new bands at 1200cm-1 appeared in FT-IR spectrum of the product indicated that the covalently C’0--bound copolymer was formed. TGA analysis showed that fullerene-functionalized polymer was a homogeneous system which increased the thermosteadiness of copolymer.

【基金】 国家自然科学基金
  • 【文献出处】 高分子学报 ,ACTA POLYMERICA SINICA , 编辑部邮箱 ,1995年05期
  • 【分类号】O635.1
  • 【被引频次】4
  • 【下载频次】90
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