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碳笼烯的高分子化──苯乙烯-烯丙基胺共聚物与C60的反应
FULLERENE-FUNCTIONALIZED POLYMER──REACTION OF C60 WITH POLY (STYRENE-CO-ALLYLAMINE)
【摘要】 碳笼烯的高分子化──苯乙烯-烯丙基胺共聚物与C_(60)的反应田慧洁,周锡煌,李福绵(北京大学化学系北京100871)关键词碳笼烯的高分子化,C_(60),苯乙烯-烯两基胺共聚物碳笼烯(fullerene)是因其具有特殊的功能性质m而颇受青睐的球簇分...
【Abstract】 Reaction of C60 with poly (styrene-co-allylamine)was studied by GPC, FT-IR and TGA methods.GPC traces demonstrated that the M.of reaction product increased and exhibited a broader molecular weight distribution.The strong new bands at 1200cm-1 appeared in FT-IR spectrum of the product indicated that the covalently C’0--bound copolymer was formed. TGA analysis showed that fullerene-functionalized polymer was a homogeneous system which increased the thermosteadiness of copolymer.
【关键词】 碳笼烯的高分子化;
C60;
苯乙烯-烯两基胺共聚物;
【Key words】 Fullerene-functionalized polymer; C60; Poly(styrene-co-allylamine);
【Key words】 Fullerene-functionalized polymer; C60; Poly(styrene-co-allylamine);
【基金】 国家自然科学基金
- 【文献出处】 高分子学报 ,ACTA POLYMERICA SINICA , 编辑部邮箱 ,1995年05期
- 【分类号】O635.1
- 【被引频次】4
- 【下载频次】90