【摘要】 对黄原胶／三价铬水凝胶在７０，８０和９０℃下的脱水行为进行了研究．脱水与凝胶的交联密度即参与交联反应的三价铬的含量有密切联系．突发脱水之后的过程可以用一级反应动力学描述，反应速度常数随三价铬的浓度和温度的增高而增大，活化能为３４．５ｋｃａｌ／ｍｏｌ．一价盐（ＮａＣｌ）的含量对脱水过程没有影响．更多还原

【Abstract】 Studies on syneresis behavior of Xantlian/Cr(Ⅲ)hydrogels have been conducted at 70,80 and 90℃. The onset of syneresis appeared at a critical Cr(Ⅲ)density in a gel and the syneresis became serious when the Cr(Ⅲ) density increased.The process of syneresis can be described by means of apperant first-order reaction and the rate constant increased with increasing the temperature and the initial Cr(Ⅲ)concentration. The apparent activation energy was about 34.5 kcal/mol.Moreover,the syneresis did not depend on the concentration of monovalent salt(NaCl).更多还原