【摘要】 聚四芳基铁卟啉的合成及催化羟化环己烷的性能研究唐渝，桂明德，朱申杰（南开大学化学系，天津，３０００７１）关键词聚卟啉，仿生催化，稳定性为提高金属卟啉在拟酶催化反应中的抗氧化破坏能力［１］，合成了在苯环２，５位带有不同取代基（ＣＨ３、ＣＨ３Ｏ、Ｃｌ、Ｂ...更多还原

【Abstract】 Six new para or meta polymeric tetra (2,5-substituted phenyl) porphyrinato iron (Ⅲ)(p-polyT(2,5-2R)PPFeCl or m-polyTPPFeCl,R=H, CH3, CH3O, Cl, Br) have been synthesized, and their catalytic properties in cyclohexane hydroxylation with PhIO were studied.A better stability of polymeric porphyrinato iron toward oxidation destruction was observed.The electron donating substituent in p-polyT(2,5-2R) PPFeCl increased the activity and selectivity of the catalyst.更多还原