【摘要】 以乙二胺为模板剂，采用Ｈ_３ＰＯ_４－ｉ－Ｃ_３Ｈ_７ＯＡｌ－Ｈ_２ＮＣＨ_２ＣＨ_２ＮＨ_２－ＨＯＣＨ_２ＣＨ_２ＯＨ非水体系，首次合成了ＡｌＰＯ_４－１２分子筛。研究了反应物配比、酸碱度及磷源、铝源等水热晶化条件对产物物相的影响，用ＸＲＤ、ＩＲ、ＳＥＭ及ＴＧ－ＤＴＡ等对产物进行了表征，对非水体系生成的ＡｌＰＯ_４－１２中有机模板剂乙二胺的化学环境进行了研究，认为乙二胺在晶体中以两种环境存在：一部分与骨架作用力较弱；另一部分与骨架以较强的氢键相作用。更多还原

【Abstract】 Hydrothermal crystallization of aluminophosphate molecule sieve（ALPO₄-12）was carried out from H₃PO₄-i-C₃H₇OAl-H₂NCH₂CH₂NH₂-HOCH₂CH₂OH system,Using aluminum triisopropoxide and phosphorous acid （85 wt%）as the aluminum and phosphoroussources.The influences of some main factors（pH,the ratio of P₂O₅/Al₂O₃ and the aluminum and phosphorous sources,etc.） on the resulting structure were studied.The product was characterized by means of X-ray powder diffraction,scanning electron mieroscope,infrared spectroscopy,differential analysis and thermogravimetric analysis. The results of investigating the crystallization of AlPO₄-12 from non-aqueous system were preliminarily summarized.We found that the organic template,H₂NCH₂CH₂NH₂,had two different kinds of environments:one interacted with the skelton by weak hydrogen-bond,the others interacted with the skelton by strong hydrogen-bond.更多还原