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7-(4,5-二甲基-2-噻唑偶氮)-8-羟基喹啉与锌显色反应的研究和应用
StUdy on the Colour Reaction of ZincWith 7-(4,5-dimethy 1-2-thiazolylazo)-8- quinolinol and its Applications
【摘要】 探讨题示试剂(DMTAQ)与锌离子的显色反应条件,当pH为5.5,在TritonX-100存在下,DMTAQ与锌离子形成红色配合物,最大吸收峰位于545nm,表观摩尔吸光系数9.4×10 ̄4L·mol ̄(-1)·cm ̄(-1),锌量在0~25μg/50mL范围内符合比尔定律。该法可用于测定人发中的微量锌。
【Abstract】 he optimum conditions of colourreaction of zinc with the reagent 7-(4,5-dimethy 1-2-thiazolylazo)-8-quinolinol(D-MTAQ) have been studied.Ared colourcomplex is formed form Zn(Ⅱ)and DM-TAQ in the prestnce of Triton X-100 atpH5.5. The complex has an absorptionmaximum at 545nm. The molar absorp-tivity is 9.4×10 ̄4L·mol ̄(-1)·cm ̄(-1),Beer’slaw is obeyed for 0~25μg/50mL of zinc. Then method has been used fof the deter-mination of trace amounts of zinc in hu-man hair.
【关键词】 7-(4;
5-二甲基-2-噻唑偶氮)-8-羟基喹啉;
分光光度法;
锌;
【Key words】 Dimethy 1-2-thia-zolylazo)-8-quinolinol; spectrophotome-try; zinc;
【Key words】 Dimethy 1-2-thia-zolylazo)-8-quinolinol; spectrophotome-try; zinc;
- 【文献出处】 分析试验室 ,ANALYTICAL LABORATORY , 编辑部邮箱 ,1995年02期
- 【分类号】Q581
- 【被引频次】9
- 【下载频次】32