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线性回归间接极谱络合滴定
Complexometric Titration in Combination With Indirect Polarography and Linear Regression
【摘要】 本文提出的方法是,根据一定的络合平衡和物料平衡,将间接极谱和线性回归应用于络合滴定,旨在扩大络合滴定的应用范围.文中对测定误差作了分析和计算,探讨了滴定点及权重选择问题.测定了Co2+、Ni2+、Mg2+、Zn2+,精密度和准确度都令人满意.
【Abstract】 Based on related complex equilibria and material balances, a complexometric titra-tion in combination with indirect polarography and linear regression is proposed to widen the application range of complexometric titration. The error problem is studied by means of computation. Selection of determination points and weight factors is discussed. The method has been applied to the determination of Co2+ ,Ni2+ ,Mg2+ and Zn2+ with RSD of 0. 11%-0. 32%
【关键词】 极谱;
络合滴定;
线性回归;
化学计量学;
【Key words】 Polarography; complexometric titration; linear regression; chemometrics;
【Key words】 Polarography; complexometric titration; linear regression; chemometrics;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1995年08期
- 【分类号】O657.14
- 【被引频次】2
- 【下载频次】25