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用铬(Ⅵ)-糗酸钾-茜素绿体系催化光度法测定痕量铬(Ⅵ)
Catalytic Spectrophotometric Determination of Trace Chromium( Ⅵ) With Chromium (Ⅵ)-Potassium Bromate-Alizarin Green System
【摘要】 基于酸性介质中溴酸钾氧化茜素绿的反应,提出了测定痕量铬(Ⅵ)的新催化光度法.方法检出限为 3.0×10-9g/mL,可测铬(Ⅵ)量的范围为 0.010.24μge/mL,应用于测定电镀废水和电镀排放水中铬(Ⅵ).
【Abstract】 A catalytic spectrophotometric method is suggested for determining trace Cr(Ⅵ) by the reaction of alizarin green oxidation in an acid medium with potassium bromate. The detection limit is 3. 0×10-9 μg/mL. The range of determination is 0. 01 -0. 24 μg/mL. The apparent activation energy of catalytic reaction is 24. 3 kJ/mol. The method has been used to determine trace Cr(Ⅵ) in electroplating waste water and drainage water
【关键词】 催化光度法;
溴酸钾;
茜素绿;
铬(Ⅵ);
【Key words】 Catalytic spectrophotometry; potassium bromate; alizarin green; chromium.;
【Key words】 Catalytic spectrophotometry; potassium bromate; alizarin green; chromium.;
【基金】 福建省自然科学基金资助课题
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,1995年07期
- 【分类号】O657.3
- 【被引频次】40
- 【下载频次】121