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乳化液膜提取铀(Ⅵ)的动力学
A study on the extraction kinetics of uranium(Ⅵ)with liquid surfactant membrane
【摘要】 用恒界面池法研究了以2-乙基己基膦酸单2-乙基己基酯为载体的乳化液膜从硫酸盐介质中提取铀(Ⅵ)的动力学.测定了外水相组成、液膜组成、搅拌器转速以及温度对提取速率的影响,得出了提取铀(Ⅵ)的速率规律,并对提取过程的速控类型及传质机制进行了讨论.
【Abstract】 The kinetics of extraction of cranium(Ⅵ) from sulfate solution with liquid surfactant membrane containing HEHEHP as a mobile carrier was investigated using Lewiscell technique. The effects of temperature, stirring speed and the component of outer-aqueous phase and liquid membrane on the rate of extraction of urnium(Ⅵ)were examined. The regularity of the extraction rate of urnium(Ⅵ) has been obtained. The rate-control type of extraction process and the matter transfer mechanism have been discussed.
【关键词】 铀;
膜法;
萃取;
化学动力学;
2-乙基己基膦酸单2-乙基己基酯;
【Key words】 uranium; membrane process; extraction; chemical kinetics; mono(2-ethylhexyl) 2-ethythexyl phosphoric acid;
【Key words】 uranium; membrane process; extraction; chemical kinetics; mono(2-ethylhexyl) 2-ethythexyl phosphoric acid;
【基金】 复旦大学原子核科学系
- 【文献出处】 复旦学报(自然科学版) , 编辑部邮箱 ,1995年03期
- 【分类号】O313
- 【被引频次】3
- 【下载频次】72