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乳化液膜提取铀(Ⅵ)的动力学

A study on the extraction kinetics of uranium(Ⅵ)with liquid surfactant membrane

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【作者】 孙永霞周祖铭

【Author】 Sun Yongxia; Zhou Zuming (Department of Nuclear Science)

【机构】 复旦大学原子核科学系

【摘要】 用恒界面池法研究了以2-乙基己基膦酸单2-乙基己基酯为载体的乳化液膜从硫酸盐介质中提取铀(Ⅵ)的动力学.测定了外水相组成、液膜组成、搅拌器转速以及温度对提取速率的影响,得出了提取铀(Ⅵ)的速率规律,并对提取过程的速控类型及传质机制进行了讨论.

【Abstract】 The kinetics of extraction of cranium(Ⅵ) from sulfate solution with liquid surfactant membrane containing HEHEHP as a mobile carrier was investigated using Lewiscell technique. The effects of temperature, stirring speed and the component of outer-aqueous phase and liquid membrane on the rate of extraction of urnium(Ⅵ)were examined. The regularity of the extraction rate of urnium(Ⅵ) has been obtained. The rate-control type of extraction process and the matter transfer mechanism have been discussed.

【基金】 复旦大学原子核科学系
  • 【分类号】O313
  • 【被引频次】3
  • 【下载频次】72
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