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CS＿2在Cu─S键中插入产物（Ph＿3P）＿2Cu（S＿2CSR）与溶剂反应的研究Ⅲ双核铜化合物［CuI（PPh＿3）（py）］＿2和［CH＿2（C＿5H＿5N）＿2］＿2［Cu＿2I＿6］的形成和
Study on the Reactions of Mononuclear Copper Complexes Formed by Insertion of CS2 into Cu-S Bonds with Various Solvents Ⅲ Formation and Crystal Structure of [CuI（PPh3）（Py）]2 and [CH2（C5H5N）2]2[Cu2I6]
【摘要】 ＣＳ＿２在Ｃｕ─Ｓ键中插入产物（Ｐｈ＿３Ｐ）＿２Ｃｕ（Ｓ＿２ＣＳＲ）（Ｒ＝Ｂｕ￣ｔ或与丙酮－Ｐｙ混合溶剂反应，获得了双核铜化合物［ＣｕＩ（ＰＰｈ＿３）（Ｐｙ）］＿２和［ＣＨ＿２（Ｃ＿５Ｈ＿５Ｎ）＿２］＿２［Ｃｕ＿２Ｉ＿６］两个化合物晶体，用Ｘ射线单晶衍射法测得它们的晶体结构。
【Abstract】 Mononuclear copper complexes with structures of（Ph3P）2 Cu（S2CSR）, formed by insertion of CS2 into Cu─S bonds,can react with a various solvents undergoing some nucleophilic reactions。 The two title compounds（Ⅳ,Ⅴ）were obtained from the reaction of starting material（R=Bu￣t,）with CH2I2-acetone mixed-solvent in the presence of pyridine and then self-assembly in the same solution. Crystal data for compound Ⅳ :space group C2/c,a=26. 112（6）,b=14. 499（3）,c=11. 357（2） ,β=95. 18（2）°,V=4282（15）A￣3 , Dc=1. 650g/cm￣3,Z =4,R=0. 0334 for 2182 independent reflections. Crystal data for compound V :space group P21/n,a=11. 389（4）,b=11. 698（5）,c=13. 227（7）A ,β=114. 99 （4）°,V=1597（13）A￣3, Dc=2. 563g/cm￣3,Z=4,R=0. 0627 for 1891 independent reflection.
【Key words】 CS2 insertion reaction； dinuclear copper complex； crystal structure；
- 【文献出处】 北京大学学报(自然科学版) ,ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS , 编辑部邮箱 ,1995年06期
- 【分类号】O621.2
- 【被引频次】2
- 【下载频次】55