【摘要】 本文叙述了具有光学活性的没药烯类倍半萜化合物（ｓ）－（－）β－没药烯（１），（Ｓ）－（－）４，４－二甲基－２－（４－甲基－３－环己烯基）－１，５－己二烯（２），（Ｒ）－（＋）β－没药烯（３），（Ｓ）－（－）－６－甲基－４－（Ｒ，Ｓ）－羟基－２－（４′－甲基－３′－环己烯基）－１－己烯（４）．（Ｓ）－（－）－６－甲基－４－酮基－２－（４′－甲基－３′－环己烯基）－１－己烯（５）的合成及结构确证。化合物（４）．（５）未见文献报道。更多还原

【Abstract】 The synthesis of optically active sesquiterpenes,(S)-(-)-β-bisabolene(1).(S)-(-)-4,4-dimethyl-2-(4′-methyl-3′-cyclohexen-1′yl)-1,5-hexadiene(2),(R)-(+)-β-bisabolene(3),(S)-(-)-6-methyl-2-(4′-methyl-3′-cyclohexen-1′-yl)-1-hepten-4-(R,S)-ol(4),(S)-(-)-6-methyl-2-(4′-methyl-3′-cyclohexen-1′-yl)-1-hepten-4-one( 5)was described in this paper.The compounds(4,5)have not been reported in the literature.Their structures were identified.更多还原