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裂解色谱法研究PMR型聚酰亚胺前体的反应过程

Pyrolysis Gas chromatographic Study on Reaction Process of PMR Type Polyimide Precursors

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【作者】 丁孟贤徐正炎张劲孟慧岚

【Author】 Ding Mengxian; Xu Zhengyan; Zhang Jin and Meng Huilang(Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022)

【机构】 中国科学院长春应用化学研究所

【摘要】 用裂解气相色谱法研究PMR型聚酰亚胺前体在反应中的化学变化过程,以裂解产物醇和环戊二烯的生成率表示酰胺化或酰亚胺化及交联的程度,结果表明,酰胺化或酰亚胺化在50℃以下不发生,在180~220℃完成,降冰片烯端基在150℃以下不发生交联反应,在280℃,10~18小时可完成交联反应。

【Abstract】 Pyrolysis gas chromatography has been used to investigate the dealcoholizationand crosslinking process of PMR type polyimide precursors,The relative amounts of the re-leased alcohol and cyclopentadiene were selected to indicate the formation of amide or imideand the remained norbonene endcaps,respectively. The results showed that the dealcoholiza-tion is a temperattire dependent process,and it began at above 50℃ and completed at 180~220℃,Whereas,the crosslinking of the end-capped norbonene is dependent both on thetemperature and time;it started at above 150℃ and completed at 280℃ for 10~18 hours.

  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1994年03期
  • 【分类号】O633.22
  • 【被引频次】1
  • 【下载频次】89
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