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弹性体型聚氨酯和聚碳酸酯共混物的形态结构

Morphologic Structure of Blends of Elastomeric Polyurethane with Polycarbonate

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【作者】 阎荣江李光杨秉新

【Author】 Yan Rongiiang; Li Guang and Yang Bingxin(Polymer Physics Laboratory,Changchun Institute of Applied Chemistry,Chinese Academy of Science,Changchun 130022)

【机构】 中国科学院长春应用化学研究所高分子物理开放实验室

【摘要】 用DSC、WAXD和SAXS研究了溶液共混的弹性体型聚氨酯(PU)/聚碳酸酯(PC)共混物的结构。结果表明,PU/PC为部分相容体系;共混过程中,溶剂DMF的诱导作用使PC形成结晶,其长周期与PU硬段形成微相的长周期相近

【Abstract】 Structure of elastomeric polyurethane(PU)/polycarbonate(PC)blends obtainedria dissolvation in DMF has been studied by DSC,wide angle X- ray diffraction(WAXD),and small angle X-ray scattering(SAXS).In the blends,the glass transition temperature ofPU increases with increasing the content of PC,the melting point of PC crystals is lowerthan that of pure PC. All the samples have a peak at the close positions on their SAXScurves. The results show that PU and PC are partially miscible and the long period of PU′smicro-phases is close to that of the solvent-induced crystal of PC.

  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,1994年03期
  • 【分类号】O633.14
  • 【被引频次】9
  • 【下载频次】188
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